Dunno if this one has been covered at all. If so, i apologize.
--You Only Live Twice. (It had ninjas, blofeld, a volcano fortress that guys rappelled down into, and sean connery's eyes painted up like a french whore...which supposedly made him look JAPANESE.)
--- Internet Superbuddies - We sure beat crack.(Tm)
I haven't watched them all yet, but I'd have to say Casino Royale (2006) was my favorite so far, simply because it was so much different while keeping to the same Bond guidelines.
In second is You Only Live Twice because it's just awesome.